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Glycerol as a Green Solvent
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Glycerol as a Green Solvent
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What is a Solvent
?
Green Chemistry
What Makes a Solvent Green?
The Making of Glycerol
Properties of Glycerol as a Solvent
Advantages
Disadvantages
What Makes Glycerol Green?
Glycerol as a Solvent in Current Industry
Organic synthesis
Enhancing Reaction Selectivity
Solvent for Biocatalysis
Catalyst Design and Recycling
Solvent for Separation
Use in Materials Chemistry
References
References
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References:
1. Buncel, E., Stairs, R. and Wilson, H.
The role of solvent in chemical reactions,
Vol. 6; Oxford University Press: London, 2003.
2. Frederick, A. et al.
Introduction to General, Organic and Biochemistry,
9th Ed.; Cengage Learning: Florence, 2009.
3. Abraham, M. and Moens, L.
Clean Solvents: Alternative Media for Chemical Reactions and Processing,
Vol 819: Oxford University Press. Michigan, 2002. p. 4-7.
4. RSC: Advancing the Chemical Sciences.
http://www.rsc.org/Publishing/
(accessed November 13, 2011).
5. Anastas, P. T.; Warner, J. C.
Green Chemistry: Theory and Practice
, Oxford University Press: New York, 1998, p.30.
6. Dura-Chem Inc.
http://duracheminc.net/GreenChemistry.aspx
(accessed November 13, 2011).
7. Capello, C., Fischer, U. and Hungerbuhler, K. What is a green solvent? A comprehensive framework for the environmental assessment of solvents.
Green Chem
.
2007,
9,
927-934.
8.The Best Solutions for Green Chemistry.
http://www.solutionsforgreenchemistry.com/
(accessed retrieved November 13, 2011).
9. Gu, Y., and Jerome, F. (2010). Glycerol as a sustainable solvent for green chemistry.
Green Chem.
2010
, 12
, 1127-1138.
10. Pagliaro, M., Rossi, M.
Future of Glycerol.;
RCS Publishing: Cambridge, UK. 2010
. [Online]
http://books.google.ca
/
books?id=TnU8SVNfFzkC&printsec=frontcover&source=gbs_ge_summary_r&cad=0#v=onepage&q&f=false
(accessed November12, 2011).
11. Robertson, S. SIDS Initial Assessment Report: Glycerol; 56-81-5; United Kingdom, 2002. [Online]
http://www.inchem.org/documents/sids/sids/56815.pdf
(accessed November14,2011).
12. Wolfson, A.;Dlugy, C.; Shotland, Y. Glycerol as a green solvent for high product yields and selectivities. Environmental Chemistry Letters. [Online] 2007, 5, 67-71
http://www.springerlink.com.ezproxy.lib.ucalgary.ca/content/x708631127t8k812/fulltext.pdf
(accessed November 14, 2011).
13. Wikipedia. Biodiesel production.
http://en.wikipedia.org/wiki/Biodiesel_production
(accessed November 14, 2011).
14. Wikipedia. Bioconcentration Factor.
http://en.wikipedia.org/wiki/Bioconcentration_factor
(accessed November14, 2011).
15. Green Parenthood. 7 Unusual Uses of Toothpaste.
http://www.greenparenthood.com/blog/2011/03/08/7-unusual-uses-of-toothpaste/
(accessed Novemer14, 2011).
16.EET Corporation. Glycerol Purification.
http://www.eetcorp.com/heepm/glycerine.htm
(accessed Nov.14, 2011).
17. Graham Engineering Corporation.
http://www.grahamengineering.com/G2RP/G2RPTechnology.htm
l (accessed November 14, 2011).
18. Advancing Green Chemistry.
http://advancinggreenchemistry.org/?attachment_id=1557
(accessed November 14, 2011).
19. Our Green Lab.
http://ourgreenlab.com/2010/07/12-principles-of-green-chemistry-not-just-for-scientists-and-chemists/
(accessed November 14,2011).
20. Hoogendoorn, A., Adriaans, T., van Kasteren, J.M.N. and Jayaraj, K.M.
Glycerine purification via bio-catalysis and column adsorption for high-quality applications.
; Ingenia: The Netherlands. 2007. [Online]
http://www.ingenia.nl/Flex/Site/Download.aspx?ID=2014
(accessed November 15, 2011).
21.Flexitank Espana.
http://www.flexitank.es/en/productos.htm
(accessed November 15, 2011).
22.Transition Technologies.
http://transitiontechnologies.tripod.com/id23.html
(accessed November 15,2011).
23.Lines, S (2009). An Exploding Market? Utilizing Waste Glycerol from the Biodiesel Production Process.
http://snrecmitigation.wordpress.com/2009/04/19/an-exploding-market-utilizing-waste-glycerol-from-the-biodiesel-production-process/
(accessed December 7, 2011).
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1. Buncel, E., Stairs, R. and Wilson, H. The role of solvent in chemical reactions, Vol. 6; Oxford University Press: London, 2003.
2. Frederick, A. et al. Introduction to General, Organic and Biochemistry, 9th Ed.; Cengage Learning: Florence, 2009.
3. Abraham, M. and Moens, L. Clean Solvents: Alternative Media for Chemical Reactions and Processing, Vol 819: Oxford University Press. Michigan, 2002. p. 4-7.
4. RSC: Advancing the Chemical Sciences. http://www.rsc.org/Publishing/ (accessed November 13, 2011).
5. Anastas, P. T.; Warner, J. C. Green Chemistry: Theory and Practice, Oxford University Press: New York, 1998, p.30.
6. Dura-Chem Inc. http://duracheminc.net/GreenChemistry.aspx (accessed November 13, 2011).
7. Capello, C., Fischer, U. and Hungerbuhler, K. What is a green solvent? A comprehensive framework for the environmental assessment of solvents. Green Chem. 2007, 9, 927-934.
8.The Best Solutions for Green Chemistry. http://www.solutionsforgreenchemistry.com/ (accessed retrieved November 13, 2011).
9. Gu, Y., and Jerome, F. (2010). Glycerol as a sustainable solvent for green chemistry. Green Chem. 2010, 12, 1127-1138.
10. Pagliaro, M., Rossi, M. Future of Glycerol.; RCS Publishing: Cambridge, UK. 2010. [Online] http://books.google.ca/
books?id=TnU8SVNfFzkC&printsec=frontcover&source=gbs_ge_summary_r&cad=0#v=onepage&q&f=false (accessed November12, 2011).
11. Robertson, S. SIDS Initial Assessment Report: Glycerol; 56-81-5; United Kingdom, 2002. [Online] http://www.inchem.org/documents/sids/sids/56815.pdf (accessed November14,2011).
12. Wolfson, A.;Dlugy, C.; Shotland, Y. Glycerol as a green solvent for high product yields and selectivities. Environmental Chemistry Letters. [Online] 2007, 5, 67-71 http://www.springerlink.com.ezproxy.lib.ucalgary.ca/content/x708631127t8k812/fulltext.pdf (accessed November 14, 2011).
13. Wikipedia. Biodiesel production. http://en.wikipedia.org/wiki/Biodiesel_production (accessed November 14, 2011).
14. Wikipedia. Bioconcentration Factor.http://en.wikipedia.org/wiki/Bioconcentration_factor (accessed November14, 2011).
15. Green Parenthood. 7 Unusual Uses of Toothpaste. http://www.greenparenthood.com/blog/2011/03/08/7-unusual-uses-of-toothpaste/ (accessed Novemer14, 2011).
16.EET Corporation. Glycerol Purification. http://www.eetcorp.com/heepm/glycerine.htm (accessed Nov.14, 2011).
17. Graham Engineering Corporation.http://www.grahamengineering.com/G2RP/G2RPTechnology.html (accessed November 14, 2011).
18. Advancing Green Chemistry. http://advancinggreenchemistry.org/?attachment_id=1557 (accessed November 14, 2011).
19. Our Green Lab. http://ourgreenlab.com/2010/07/12-principles-of-green-chemistry-not-just-for-scientists-and-chemists/ (accessed November 14,2011).
20. Hoogendoorn, A., Adriaans, T., van Kasteren, J.M.N. and Jayaraj, K.M. Glycerine purification via bio-catalysis and column adsorption for high-quality applications.; Ingenia: The Netherlands. 2007. [Online] http://www.ingenia.nl/Flex/Site/Download.aspx?ID=2014 (accessed November 15, 2011).
21.Flexitank Espana. http://www.flexitank.es/en/productos.htm (accessed November 15, 2011).
22.Transition Technologies. http://transitiontechnologies.tripod.com/id23.html (accessed November 15,2011).
23.Lines, S (2009). An Exploding Market? Utilizing Waste Glycerol from the Biodiesel Production Process.
http://snrecmitigation.wordpress.com/2009/04/19/an-exploding-market-utilizing-waste-glycerol-from-the-biodiesel-production-process/ (accessed December 7, 2011).
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